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Ch.16 - Aqueous Equilibria: Acids & Bases
Chapter 16, Problem 133

Classify each of the following salt solutions as neutral, acidic, or basic. See Appendix C for values of equilibrium constants. (a) NH4F (b) (NH4)2SO3

Verified step by step guidance
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Step 1: Identify the ions present in each salt solution. For NH4F, the ions are NH4+ and F-. For (NH4)2SO3, the ions are NH4+ and SO3^2-.
Step 2: Determine the nature of each ion. NH4+ is the conjugate acid of NH3, a weak base, making NH4+ a weak acid. F- is the conjugate base of HF, a weak acid, making F- a weak base. SO3^2- is the conjugate base of HSO3-, a weak acid, making SO3^2- a weak base.
Step 3: Consider the relative strengths of the acidic and basic ions. For NH4F, compare the acid strength of NH4+ with the base strength of F-. For (NH4)2SO3, compare the acid strength of NH4+ with the base strength of SO3^2-.
Step 4: Use equilibrium constants (Ka and Kb) to determine which ion has a stronger effect on the pH. If Ka of NH4+ is greater than Kb of F-, the solution is acidic. If Kb of F- is greater, the solution is basic. Similarly, compare Ka of NH4+ with Kb of SO3^2- for (NH4)2SO3.
Step 5: Classify each solution based on the stronger ion effect. If the acidic ion is stronger, the solution is acidic. If the basic ion is stronger, the solution is basic. If they are equal, the solution is neutral.

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Acid-Base Theory

Acid-base theory explains the behavior of acids and bases in solution. According to the Brønsted-Lowry theory, acids are proton donors while bases are proton acceptors. This concept is essential for classifying salt solutions, as the nature of the ions derived from the salts can influence the pH of the solution.
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Bronsted-Lowry Acid-Base Theory

Salt Hydrolysis

Salt hydrolysis occurs when a salt dissolves in water and its ions interact with water molecules, potentially altering the pH of the solution. Depending on the strength of the acid and base from which the salt is derived, the resulting solution can be acidic, basic, or neutral. Understanding hydrolysis is crucial for determining the pH of the given salt solutions.
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Equilibrium Constants

Equilibrium constants (K) quantify the extent of a reaction at equilibrium and are vital for predicting the behavior of acids and bases in solution. For example, the Kb of a base and the Ka of its conjugate acid can be used to assess the strength of the resulting solution. Appendix C provides these constants, which are necessary for classifying the salts in the question.
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Equilibrium Constant K