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Ch.14 - Chemical Kinetics
Chapter 14, Problem 119

Sulfur dioxide is oxidized to sulfur trioxide in the following sequence of reactions: 2 SO2(g) + 2 NO2(g) → 2 SO3(g) + 2 NO(g) 2 NO(g) + O2(g) → 2 NO2(g). (b) Identify any molecule that acts as a catalyst or intermediate in this reaction.

Verified step by step guidance
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Step 1: Understand the role of a catalyst and an intermediate in a chemical reaction. A catalyst is a substance that increases the rate of a reaction without being consumed in the process. An intermediate is a species that is formed in one step of a reaction mechanism and consumed in another.
Step 2: Analyze the given reactions to identify any species that appear in both reactions. Look for molecules that are produced in one reaction and consumed in another, as these are potential intermediates.
Step 3: Examine the first reaction: 2 SO2(g) + 2 NO2(g) → 2 SO3(g) + 2 NO(g). Notice that NO is produced in this reaction.
Step 4: Examine the second reaction: 2 NO(g) + O2(g) → 2 NO2(g). Notice that NO is consumed in this reaction, and NO2 is regenerated.
Step 5: Conclude that NO is an intermediate because it is produced in the first reaction and consumed in the second, while NO2 acts as a catalyst because it is consumed in the first reaction and regenerated in the second.

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Catalysts

A catalyst is a substance that increases the rate of a chemical reaction without being consumed in the process. It works by providing an alternative reaction pathway with a lower activation energy. In the context of the given reactions, identifying a catalyst involves recognizing any species that facilitates the conversion of reactants to products without undergoing permanent change.
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Intermediates

An intermediate is a species that is formed during the reaction and is consumed in subsequent steps. It exists only transiently and is not present in the overall balanced equation. In the provided reactions, identifying intermediates requires analyzing the sequence to find any molecules that appear in one step and are used up in another.
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Reaction Mechanism Example

Reaction Mechanism

A reaction mechanism is a detailed description of the steps involved in a chemical reaction, including the sequence of elementary reactions. Understanding the mechanism helps in identifying catalysts and intermediates, as it outlines how reactants are transformed into products. In this case, analyzing the two given reactions will reveal the roles of various molecules throughout the process.
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