Here are the essential concepts you must grasp in order to answer the question correctly.
Polarity of Solvents
Solubility is greatly influenced by the polarity of solvents. Water is a polar solvent, meaning it has a significant dipole moment due to its molecular structure, which allows it to interact well with other polar substances. In contrast, tetrachloromethane (CCl₄) is a nonpolar solvent, which interacts more effectively with nonpolar solutes like Br₂, leading to higher solubility.
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Like Dissolves Like Principle
The principle of 'like dissolves like' states that polar solvents dissolve polar solutes, while nonpolar solvents dissolve nonpolar solutes. Since Br₂ is a nonpolar molecule, it is more soluble in nonpolar solvents like CCl₄ than in polar solvents like water. This principle helps predict solubility behavior based on the nature of the solute and solvent.
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Intermolecular Forces
Intermolecular forces play a crucial role in solubility. In water, hydrogen bonding and dipole-dipole interactions dominate, which do not favor the dissolution of nonpolar substances like Br₂. In CCl₄, the weak London dispersion forces allow for better interaction with Br₂, facilitating its solubility in the nonpolar environment.
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