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Ch.12 - Solids and Solid-State Materials
Chapter 12, Problem 8

The following diagrams represent the electron population ofmolecular orbitals for different substances. What diagram correspondsto magnesium oxide, germanium, and tin? (LO 12.8)Diagrams showing electron populations in molecular orbitals for tin, magnesium oxide, and germanium.
(a) Diagram 1 = tin, diagram 2 = magnesium oxide,diagram 3 = germanium(b) Diagram 1 = germanium, diagram 2 = magnesiumoxide, diagram 3 = tin(c) Diagram 1 = germanium, diagram 2 = tin, diagram3 = magnesium oxide(d) Diagram 1 = magnesium oxide, diagram 2 = tin,diagram 3 = germanium

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1
Identify the electron configuration of magnesium oxide, germanium, and tin.
Analyze the molecular orbital diagrams provided in the image.
Compare the electron configurations of the substances with the electron populations in the molecular orbitals.
Match the electron configurations to the appropriate diagrams based on the number of electrons and their arrangement in the molecular orbitals.
Select the correct option (a, b, c, or d) that corresponds to the identified diagrams for magnesium oxide, germanium, and tin.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Molecular Orbitals

Molecular orbitals are formed by the combination of atomic orbitals when atoms bond together. They can be classified as bonding, antibonding, or non-bonding, depending on the energy levels and electron configurations. Understanding how electrons populate these orbitals is crucial for predicting the chemical properties and reactivity of molecules.
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Electron Configuration

Electron configuration describes the distribution of electrons in an atom or molecule's orbitals. It follows specific rules, such as the Aufbau principle, Pauli exclusion principle, and Hund's rule, which dictate how electrons fill available energy levels. This configuration is essential for determining the stability and bonding characteristics of elements like magnesium oxide, germanium, and tin.
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Periodic Trends

Periodic trends refer to the predictable patterns in elemental properties observed in the periodic table, such as electronegativity, atomic radius, and ionization energy. These trends arise from the arrangement of electrons and the effective nuclear charge experienced by them. Recognizing these trends helps in understanding the behavior of elements in bonding and their corresponding molecular orbital diagrams.
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Related Practice
Textbook Question
Niobium oxide crystallizes in the following cubic unit cell:

What is the formula of niobium oxide, and what is the oxidationstate of niobium? (LO 12.5)(a) NbO, Nb = +2 (b) Nb2O, Nb = +2(c) NbO2, Nb = +4 (d) Nb2O3, Nb = +3
Textbook Question
The following diagrams represent the electron population ofthe composite s–d band for three metals—Ag, Mo, and Y:

Which diagram corresponds to which metal? (LO 12.7)(a) Ag = 3, Mo = 1, Y = 2(b) Ag = 2, Mo = 1, Y = 3(c) Ag = 2, Mo = 3, Y = 1(d) Ag = 1, Mo = 2, Y = 3
Textbook Question
Examine diagrams for the electron population of the composite s–d band for three metals in question 6. Which metal has the highest melting point? (LO 12.7) (a) Metal 1 (b) Metal 2 (c) Metal 3

Textbook Question
The molecular orbital diagram of a doped semiconductor is shown below. If the semiconductor is silicon, does the diagram represent n-type or p-type doping and which of the following elements could be dopant? (LO 12.9)

(a) n-type, As (b) n-type, Ga (c) p-type, As (d) p-type, Ga
Textbook Question
If the band-gap energy of a gallium phosphide (GaP) semiconductor is 222 kJ/mol, calculate the wavelength of light emitted in a GaP light-emitting diode (LED). (LO 12.11) (a) 186 nm (b) 245 nm (c) 539 nm (d) 854 nm
Textbook Question
A superconductor is a material that loses all electrical resistance below a characteristic temperature called the superconducting transitiontemperature. Which graph represents the behavior of a superconductor? (LO 12.13)(a)

(b)

(c)

(d)