Problem 70c
An experiment called the Stern–Gerlach experiment helped establish the existence of electron spin. In this experiment, a beam of silver atoms is passed through a magnetic field, which deflects half of the silver atoms in one direction and half in the opposite direction. The separation between the two beams increases as the strength of the magnetic field increases. (c) Would this experiment work for a beam of fluorine (F) atoms?
Problem 71
What is the maximum number of electrons that can occupy each of the following subshells? a. 3p, b. 5d, c. 2s, d. 4f.
Problem 72
What is the maximum number of electrons in an atom that can have the following quantum numbers? a. n = 3, ml = -2; b. n = 4, l = 3; c. n = 5, l = 3, ml = 2; d. n = 4, l = 1, ml = 0.
Problem 73a
(a) What are 'valence electrons'?
Problem 73b
(b) What are 'core electrons'?
Problem 73c
(c) What does each box in an orbital diagram represent?
Problem 74a
For each element, indicate the number of valence electrons, core electrons, and unpaired electrons in the ground state: a. nitrogen
Problem 74c
For each element, indicate the number of valence electrons, core electrons, and unpaired electrons in the ground state: c. chlorine
- Write the condensed electron configurations for the following atoms, using the appropriate noble-gas core abbreviations: (a) Cs, (b) Ni, (c) Se, (d) Cd, (e) U, (f) Pb.
Problem 75
Problem 76a,b,c,d,e
Write the condensed electron configurations for the following atoms and indicate how many unpaired electrons each has: (a) Mg (b) Ge (c) Br (d) V (e) Y.
Problem 76f
Write the condensed electron configurations for the following atoms and indicate how many unpaired electrons each has: (f) Lu.
Problem 77a,b
Identify the specific element that corresponds to each of the following electron configurations and indicate the number of unpaired electrons for each: (a) 1s22s2 (b) 1s22s22p4
Problem 77c
Identify the specific element that corresponds to each of the following electron configurations and indicate the number of unpaired electrons for each: (c) 3Ar44s13d5
Problem 77d
Identify the specific element that corresponds to each of the following electron configurations and indicate the number of unpaired electrons for each: (d) 3Kr45s24d105p4.
Problem 79b
The following do not represent valid ground-state electron configurations for an atom either because they violate the Pauli exclusion principle or because orbitals are not filled in order of increasing energy. Indicate which of these two principles is violated in each example. b. 3Xe46s25d4
Problem 80b
The following electron configurations represent excited states. Identify the element and write its ground-state condensed electron configuration. (b) 3Ar44s13d104p25p1
Problem 81a1
Consider the two waves shown here, which we will consider to represent two electromagnetic radiations: (a) What is the wavelength of wave A?
Problem 81b1
Consider the two waves shown here, which we will consider to represent two electromagnetic radiations: (b) What is the frequency of wave A?
Problem 82b
If you put 120 volts of electricity through a pickle, the pickle will smoke and start glowing orange-yellow. The light is emitted because sodium ions in the pickle become excited; their return to the ground state results in light emission. b. What is the energy of 1.00 mol of these photons? (A mole of photons is called an Einstein.)
Problem 83c
Certain elements emit light of a specific wavelength when they are burned or heated in a non-luminous flame. Historically, chemists used such emission wavelengths to determine whether specific elements were present in a sample. Some characteristic wavelengths for a few of the elements are given in the following table:
Ag 328.1 nm Fe 372.0 nm
Au 267.6 nm K 404.7 nm
Ba 455.4 nm Mg 285.2 nm
Ca 422.7 nm Na 589.6 nm
Cu 324.8 nm Ni 341.5 nm
(c) When burned, a sample of an unknown substance is found to emit light of frequency 6.58 * 1014 s-1. Which of these elements is probably in the sample?
Problem 84
In August 2011, the Juno spacecraft was launched from Earth with the mission of orbiting Jupiter, arriving nearly five years later in July of 2016. The distance between the two planets varies depending on where each planet is in its orbit, but at the closest, the distance between Jupiter and Earth is 391 million miles. What is the minimum amount of time it takes for a transmitted signal from Juno to reach the Earth?
- Is the observation that UV-B radiation is a more important cause of sunburn in humans than UV-A radiation consistent with the answer to part (c)?
Problem 85
Problem 86
The watt is the derived SI unit of power, the measure of energy per unit time: 1 W=1 J/s. A semiconductor laser in a CD player has an output wavelength of 780 nm and a power level of 0.10 mW. How many photons strike the CD surface during the playing of a CD 69 minutes in length?
Problem 88a
In an experiment to study the photoelectric effect, a scientist measures the kinetic energy of ejected electrons as a function of the frequency of radiation hitting a metal surface. She obtains the following plot. The point labeled 'n0' corresponds to light with a wavelength of 542 nm. (a) What is the value of n0 in s - 1?
Problem 89a
Consider a transition in which the electron of a hydrogen atom is excited from n = 1 to n = ∞. (a) What is the end result of this transition?
Problem 89b
Consider a transition in which the electron of a hydrogen atom is excited from n = 1 to n = ∞. (b) What is the wavelength of light that must be absorbed to accomplish this process?
Problem 89d
Consider a transition in which the electron of a hydrogen atom is excited from n = 1 to n = ∞. (d) How are the results of parts (b) and (c) related to the plot shown in Exercise 6.88?
Problem 90c
The human retina has three types of receptor cones, each sensitive to a different range of wavelengths of visible light, as shown in this figure (the colors are merely to differentiate the three curves from one another; they do not indicate the actual colors represented by each curve):
(c) Explain why the sky appears blue even though all wavelengths of solar light are scattered by the atmosphere.
Problem 91a
The series of emission lines of the hydrogen atom for which nf = 3 is called the Paschen series. (a) Determine the region of the electromagnetic spectrum in which the lines of the Paschen series are observed.
Problem 91b
The series of emission lines of the hydrogen atom for which nf = 3 is called the Paschen series. (b) Calculate the wavelengths of the first three lines in the Paschen series—those for which ni = 4, 5, and 6.
Ch.6 - Electronic Structure of Atoms