Ethanol (C2H5OH) is blended with gasoline as an automobile fuel. (d) Calculate the mass of CO2 produced per kJ of heat emitted.
Methanol (CH3OH) is used as a fuel in race cars. (d) Calculate the mass of CO2 produced per kJ of heat emitted.


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Key Concepts
Combustion Reaction
Stoichiometry
Energy Release in Combustion
Methanol (CH3OH) is used as a fuel in race cars. (b) Calculate the standard enthalpy change for the reaction, assuming H2O(g) as a product.
Methanol (CH3OH) is used as a fuel in race cars. (c) Calculate the heat produced by combustion per liter of methanol. Methanol has a density of 0.791 g/mL.
Ethane, C2H6, is an alkane with one C─C bond and six C─H bonds (Section 2.9). a. Use enthalpies of formation given in Appendix C to calculate Δ𝐻 for the reaction C2H6(𝑔)→2C(𝑔)+6H(𝑔). b. Use the result from part (a) and the value of 𝐷(C─H) from Table 5.4 to estimate the bond enthalpy 𝐷(C─C). c. How large is the difference between the value calculated for in part (b) and the value given in Table 5.4?
Use bond enthalpies in Table 5.4 to estimate H for each of the following reactions: (a)
Consider the reaction 2 H2(g) + O2(g) → 2 H2O(l). (a) Use the bond enthalpies in Table 5.4 to estimate H for this reaction, ignoring the fact that water is in the liquid state.