Skip to main content
Ch.21 - Nuclear Chemistry
Chapter 21, Problem 43

Potassium-40 decays to argon-40 with a half-life of 1.27 * 109 yr. What is the age of a rock in which the mass ratio of 40Ar to 40K is 4.2?

Verified step by step guidance
1
Identify the decay process: Potassium-40 (\(^{40}\text{K}\)) decays to Argon-40 (\(^{40}\text{Ar}\)) through a radioactive decay process.
Use the given half-life of \(^{40}\text{K}\), which is 1.27 \times 10^9\) years, to determine the decay constant (\(\lambda\)) using the formula \(\lambda = \frac{\ln(2)}{\text{half-life}}\).
Apply the formula for radioactive decay: \(N_t = N_0 e^{-\lambda t}\), where \(N_t\) is the number of \(^{40}\text{K}\) atoms remaining, \(N_0\) is the initial number of \(^{40}\text{K}\) atoms, and \(t\) is the time elapsed.
Relate the mass ratio of \(^{40}\text{Ar}\) to \(^{40}\text{K}\) to the number of atoms: \(\frac{N_{\text{Ar}}}{N_{\text{K}}} = 4.2\), where \(N_{\text{Ar}}\) is the number of \(^{40}\text{Ar}\) atoms and \(N_{\text{K}}\) is the number of \(^{40}\text{K}\) atoms.
Solve for the age of the rock (\(t\)) using the relationship between \(N_{\text{Ar}}\), \(N_{\text{K}}\), and the decay constant \(\lambda\).

Verified video answer for a similar problem:

This video solution was recommended by our tutors as helpful for the problem above.
Video duration:
5m
Was this helpful?

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Radioactive Decay

Radioactive decay is the process by which an unstable atomic nucleus loses energy by emitting radiation. This decay occurs at a predictable rate characterized by the half-life, which is the time required for half of the radioactive substance to transform into a different element or isotope.
Recommended video:
Guided course
03:00
Rate of Radioactive Decay

Half-Life

Half-life is a specific time period in which half of a given quantity of a radioactive isotope decays into its daughter product. For potassium-40, the half-life is 1.27 billion years, meaning that after this time, half of the original potassium-40 will have decayed into argon-40.
Recommended video:
Guided course
02:17
Zero-Order Half-life

Mass Ratio and Age Calculation

The mass ratio of daughter to parent isotopes can be used to determine the age of a rock through the equation derived from the decay law. By knowing the mass ratio of argon-40 to potassium-40 and the half-life, one can calculate the time elapsed since the rock formed, providing an estimate of its age.
Recommended video:
Guided course
02:14
Neutron-Proton Ratio