Textbook Question
The value of Ka for nitrous acid (HNO2) at 25 °C is given in Appendix D. (c) What is the value of ΔG at equilibrium?
Ch.19 - Chemical Thermodynamics
Chapter 19, Problem 84d
The Kb for methylamine (CH3NH2) at 25 °C is given in Appendix D. (d) What is the value of ΔG when [H+] = 6.7 × 10-9 M, [CH3NH3+] = 2.4 × 10-3 M, and [CH3NH2] = 0.098 M?
Verified step by step guidance1
Identify the reaction for the dissociation of methylamine (CH3NH2) in water: CH3NH2 + H2O ⇌ CH3NH3+ + OH-. The equilibrium constant for this reaction is the base dissociation constant, Kb.
Use the relationship between the equilibrium constant (K) and the Gibbs free energy change (ΔG) given by the equation: ΔG = -RT ln(K), where R is the universal gas constant (8.314 J/mol·K) and T is the temperature in Kelvin.
Calculate the reaction quotient (Q) using the given concentrations: Q = ([CH3NH3+][OH-])/[CH3NH2]. Note that [OH-] can be found using the relation [OH-] = Kw/[H+], where Kw is the ion product of water (1.0 × 10^-14 at 25 °C).
Determine the equilibrium constant (K) using the given Kb value for methylamine from Appendix D. This value is necessary to compare with the reaction quotient (Q).
Calculate ΔG using the equation ΔG = ΔG° + RT ln(Q), where ΔG° is the standard Gibbs free energy change calculated from Kb, and Q is the reaction quotient calculated in the previous step.
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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Equilibrium Constant (K)
The equilibrium constant (K) quantifies the ratio of concentrations of products to reactants at equilibrium for a given reaction. For a base like methylamine, Kb indicates its strength as a base, reflecting how well it accepts protons in solution. Understanding Kb is essential for calculating the Gibbs free energy change (ΔG) in the context of acid-base equilibria.
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Equilibrium Constant K
Gibbs Free Energy (ΔG)
Gibbs free energy (ΔG) is a thermodynamic potential that measures the maximum reversible work obtainable from a thermodynamic system at constant temperature and pressure. It is calculated using the formula ΔG = ΔG° + RT ln(Q), where Q is the reaction quotient. This concept is crucial for determining the spontaneity of a reaction and how it relates to the concentrations of reactants and products.
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Reaction Quotient (Q)
The reaction quotient (Q) is a measure of the relative concentrations of products and reactants at any point in a reaction, similar to K but not necessarily at equilibrium. It is calculated using the same expression as K but with the current concentrations. Comparing Q to K helps predict the direction of the reaction and is vital for calculating ΔG in the given scenario.
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Related Practice
Textbook Question
The value of Ka for nitrous acid (HNO2) at 25 °C is given in Appendix D. (d) What is the value of ΔG when [H+] = 5.0⨉10-2 M, [NO2-] = 6.0⨉10-4 M, and [HNO2] = 0.20 M?
Textbook Question
The Kb for methylamine (CH3NH2) at 25 °C is given in Appendix D. (a) Write the chemical equation for the equilibrium that corresponds to Kb.
Textbook Question
(a) Which of the thermodynamic quantities T, E, q, w, and S are state functions? (b) Which depend on the path taken from one state to another?
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Textbook Question
(d) For a reversible isothermal process, write an expression for ΔE in terms of q and w and an expression for ΔS in terms of q and T.
Textbook Question
The crystalline hydrate Cd(NO3)2⋅4 H2O(s) loses water when placed in a large, closed, dry vessel at room temperature: Cd(NO3)2⋅4 H2O(s) → Cd(NO3)2(s) + 4 H2O(g) This process is spontaneous and ΔH° is positive at room temperature.
(a) What is the sign of ΔS° at room temperature?