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Ch.20 - Nuclear Chemistry
Chapter 20, Problem 114

A proposed nuclear theory suggests that the relative abun-dances of the uranium isotopes 235U and 238U were approximately equal at the time they were formed. Today, the observed ratio of these isotopes is 7.25 x 10^-3. Give that the half-lives for radioactive decay are 7.04 x 19^8 are y for and 4.47 x 10^9 y for , calculate the age of the elements.

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Step 1: Understand the problem. We are given the current ratio of the isotopes 235U and 238U, and their respective half-lives. We are asked to calculate the age of the elements, which is the time elapsed since the isotopes were formed.
Step 2: Use the formula for radioactive decay, which is N = N0 * (1/2)^(t/T), where N is the final amount, N0 is the initial amount, t is the time elapsed, and T is the half-life. In this case, we know that the initial amounts of 235U and 238U were equal, so we can set up a ratio of the final amounts: (235U/238U) = (1/2)^(t/T_235U) / (1/2)^(t/T_238U).
Step 3: Substitute the given values into the equation. We know that the current ratio of 235U to 238U is 7.25 x 10^-3, the half-life of 235U is 7.04 x 10^8 years, and the half-life of 238U is 4.47 x 10^9 years.
Step 4: Simplify the equation. The terms with base (1/2) can be combined by subtracting the exponents, giving us (235U/238U) = (1/2)^(t/T_235U - t/T_238U).
Step 5: Solve the equation for t. This will involve taking the logarithm of both sides and rearranging the equation to isolate t. The final equation will be t = (log(235U/238U) / log(1/2)) * (T_235U*T_238U / (T_238U - T_235U)).

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Radioactive Decay

Radioactive decay is the process by which an unstable atomic nucleus loses energy by emitting radiation. This decay occurs at a predictable rate characterized by the half-life, which is the time required for half of the radioactive nuclei in a sample to decay. Understanding this concept is crucial for calculating the age of materials using isotopic ratios.
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Rate of Radioactive Decay

Half-Life

The half-life of a radioactive isotope is the time it takes for half of a sample of that isotope to decay into its daughter products. Each isotope has a unique half-life, which is constant and independent of the initial amount of the substance. This concept is essential for determining the age of geological or archaeological samples through radiometric dating.
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Zero-Order Half-life

Isotope Ratios

Isotope ratios refer to the relative abundances of different isotopes of an element in a sample. In the context of radiometric dating, comparing the ratio of parent isotopes (like 235U) to daughter isotopes (like 207Pb) allows scientists to estimate the time elapsed since the formation of the sample. This ratio is critical for calculating the age of elements based on their decay rates.
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Related Practice
Textbook Question
Nitrogen-16 is formed in the cooling water flowing through a hot reactor core in a nuclear power plant. It is formed when oxygen captures a neutron and then emits a b par-ticle. Determine the activity of 50.0 mg of 16N in units of Bq and Ci.
Textbook Question
A small sample of wood from an archaeological site in Clo-vis, New Mexico, was burned in O2 and the CO2 produced was bubbled through a solution of Ba(OH)2 to produce a precipitation of BaCO3. When the BaCO3 was collected by filtration, a 1.000 g sample was found to have a radioactivity of 4.0 x 10^-5 Bq. The half-life of 14C is 5715 y, and living organisms have a radioactivity due to 14C if 15.3 disintegrations/min per gram of carbon. If the analysis was carried out in 1960, what is the date of the Clovis site?
Textbook Question
Polonium-210, a naturally occurring radioisotope, is an alpha emitter, with t1/2=138 d. Assume that a sample fo 210Po with a mass of 0.700 mg was placed ina 250.0-mL flask, which was evacuated, sealed, and allowed to sit undisturbed. What would the pressure be inside the flask (in mmHg) at 20 degrees Celsius after 365 days if all the alpha particles emitted has become helium atoms?
Textbook Question
Imagine that you have a 0.007 50 M aqueous MgCl2 solu-tion, prepared so that it contains a small amount of radio-active 28Mg. The half-life of 28Mg is 20.91 h, and the initial activity of the MgCl2 solution is 0.112 mCi>mL. Assume that 20.00 mL of this MgCl2 solution is added to 15.00 mL of 0.012 50 M aqueous Na2CO3 solution and that the resultant precipitate is then removed by filtration to yield a clear filtrate. After a long break to go for a run, you find that the activity of the filtrate measured 2.40 h after begin-ning the experiment is 0.029 mCi>mL. What are the molar concentrations of Mg2+ and CO32- in the filtrate, and what is the solubility product constant of MgCO3?
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