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Multiple Choice
Which of the following substances would you predict to have a higher boiling point, and why?
A
Oxygen (O2) due to its diatomic nature
B
Water (H2O) due to hydrogen bonding
C
Methane (CH4) due to its nonpolar nature
D
Carbon dioxide (CO2) due to its linear structure
Verified step by step guidance
1
Identify the types of intermolecular forces present in each substance: Water (H2O) has hydrogen bonding, a strong intermolecular force. Oxygen (O2), Methane (CH4), and Carbon dioxide (CO2) primarily exhibit London dispersion forces, which are weaker.
Understand that substances with stronger intermolecular forces generally have higher boiling points because more energy is required to break these forces during the phase transition from liquid to gas.
Compare the molecular structures: Water (H2O) is a polar molecule with hydrogen bonds, while Methane (CH4) and Carbon dioxide (CO2) are nonpolar and rely on weaker dispersion forces. Oxygen (O2) is also nonpolar and diatomic, relying on dispersion forces.
Recognize that hydrogen bonding in water significantly increases its boiling point compared to the other substances, which only have dispersion forces.
Conclude that Water (H2O) has the highest boiling point among the given substances due to the presence of hydrogen bonding, which is stronger than the dispersion forces present in O2, CH4, and CO2.