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Multiple Choice
For a given substance:
A
ΔHfreezing < ΔHfus
B
ΔHsub = ΔHfus + ΔHvap
C
ΔHvap < ΔHfus
D
ΔHsub < ΔHvap
Verified step by step guidance
1
Understand the terms: ΔHfus is the enthalpy change for fusion (melting), ΔHvap is the enthalpy change for vaporization, and ΔHsub is the enthalpy change for sublimation.
Recall that sublimation is the process where a substance transitions directly from solid to gas. The enthalpy change for sublimation (ΔHsub) can be calculated using the sum of the enthalpy changes for fusion and vaporization: ΔHsub = ΔHfus + ΔHvap.
Analyze the given inequalities: ΔHfreezing < ΔHfus and ΔHvap < ΔHfus. These suggest that the enthalpy change for freezing is less than that for fusion, and the enthalpy change for vaporization is less than that for fusion.
Consider the relationship between these enthalpy changes: Since ΔHsub = ΔHfus + ΔHvap, the enthalpy change for sublimation is the sum of the enthalpy changes for fusion and vaporization.
Use these relationships to understand the energy requirements for phase changes: The enthalpy change for sublimation is greater than either fusion or vaporization alone, as it involves both processes.