Skip to main content
Ch.9 - Periodic Properties of the Elements
Chapter 9, Problem 103

The lightest noble gases, such as helium and neon, are completely inert—they do not form any chemical compounds whatsoever. In contrast, the heavier noble gases do form a limited number of compounds. Explain this difference in terms of trends in fundamental periodic properties.

Verified step by step guidance
1
insert step 1> The noble gases are located in Group 18 of the periodic table and are known for their lack of reactivity due to having a complete valence electron shell.
insert step 2> Helium and neon, the lightest noble gases, have very high ionization energies and small atomic radii, making it difficult for them to participate in chemical bonding.
insert step 3> As you move down the group from helium to heavier noble gases like xenon and radon, the atomic size increases, and the ionization energy decreases.
insert step 4> The decrease in ionization energy and increase in atomic size for heavier noble gases make it easier for them to form compounds, as they can more readily share or transfer electrons.
insert step 5> Additionally, the presence of d and f orbitals in heavier noble gases allows for expanded valence shells, facilitating the formation of compounds under certain conditions.

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Noble Gas Stability

Noble gases are characterized by having a complete valence shell, which makes them highly stable and unreactive. Helium and neon, being the lightest noble gases, have full outer electron shells that do not seek additional electrons, resulting in their inert nature. In contrast, heavier noble gases have larger atomic radii and can exhibit some reactivity under specific conditions, leading to the formation of compounds.
Recommended video:
Guided course
00:59
Noble Gas Compounds

Atomic Size and Reactivity

As you move down the periodic table, atomic size increases due to the addition of electron shells. This increase in size affects the reactivity of noble gases; heavier noble gases have more diffuse electron clouds, which can lead to interactions with other elements. The larger atomic radius can allow for some degree of polarization, enabling these gases to form weak bonds in certain compounds.
Recommended video:
Guided course
02:10
Atom Structure

Electronegativity and Bond Formation

Electronegativity is a measure of an atom's ability to attract and hold onto electrons. While noble gases generally have low electronegativity, heavier noble gases can exhibit slight electronegativity due to their larger size and the presence of more electrons. This allows them to engage in limited bonding with highly electronegative elements, resulting in the formation of a few stable compounds.
Recommended video:
Guided course
02:10
Electronegativity Trends