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Ch.11 - Chemical Bonding II: Molecular Shapes, VSEPR & MO Theory
Chapter 11, Problem 42b

Determine the molecular geometry about each interior atom and sketch each molecule. b. N2H2 (skeletal structure HNNH)

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Determine the total number of valence electrons in the molecule. Nitrogen (N) has 5 valence electrons and hydrogen (H) has 1 valence electron. Calculate the total for N2H2.
Draw the Lewis structure for N2H2. Start by connecting the atoms with single bonds according to the skeletal structure HNNH.
Complete the octets for the nitrogen atoms by adding lone pairs of electrons, ensuring that the total number of valence electrons is used.
Determine the molecular geometry around each nitrogen atom. Consider the electron groups (bonds and lone pairs) around each nitrogen atom to predict the geometry using VSEPR theory.
Sketch the molecule based on the determined geometry, showing the arrangement of atoms and lone pairs around each nitrogen atom.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

VSEPR Theory

Valence Shell Electron Pair Repulsion (VSEPR) Theory is a model used to predict the geometry of individual molecules based on the repulsion between electron pairs in the valence shell of the central atom. According to this theory, electron pairs will arrange themselves as far apart as possible to minimize repulsion, leading to specific molecular shapes.
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Molecular Geometry

Molecular geometry refers to the three-dimensional arrangement of atoms within a molecule. It is determined by the number of bonding pairs and lone pairs of electrons around the central atom, which influences the angles between bonds and the overall shape of the molecule, such as linear, bent, or tetrahedral.
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Lewis Structures

Lewis structures are diagrams that represent the bonding between atoms in a molecule and the lone pairs of electrons that may exist. They provide a visual representation of the arrangement of electrons, helping to predict molecular geometry and the connectivity of atoms, which is essential for understanding the structure of compounds like N2H2.
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