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Ch.9 - Chemical Bonding I: The Lewis Model
Chapter 9, Problem 89

Carbon ring structures are common in organic chemistry. Draw a Lewis structure for each carbon ring structure, including any necessary resonance structures. a. C4H8 b. C4H4 c. C6H12 d. C6H6

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1
Identify the molecular formula for benzene, which is C_6H_6, indicating it is a six-carbon ring with alternating double bonds.
Recognize that benzene is a planar, cyclic molecule with a hexagonal ring structure, where each carbon atom is bonded to one hydrogen atom.
Draw a hexagon to represent the carbon ring, and place a carbon atom at each vertex of the hexagon.
Add alternating double bonds between the carbon atoms in the ring to represent the delocalized pi electrons, which is a key feature of benzene's resonance.
Draw resonance structures by shifting the position of the double bonds around the ring, showing that the electrons are delocalized across the entire structure.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Lewis Structures

Lewis structures are diagrams that represent the bonding between atoms in a molecule and the lone pairs of electrons that may exist. They use dots to represent electrons and lines to represent bonds between atoms. Understanding how to draw Lewis structures is essential for visualizing molecular geometry and predicting reactivity.
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Resonance Structures

Resonance structures are different ways of drawing the same molecule that illustrate the delocalization of electrons. In molecules like benzene (C6H6), resonance structures help depict the equal distribution of electron density across the carbon atoms, which contributes to the molecule's stability and unique properties. Recognizing resonance is crucial for understanding the behavior of organic compounds.
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Hydrocarbons

Hydrocarbons are organic compounds consisting entirely of hydrogen and carbon. They can be classified into aliphatic (straight or branched chains) and aromatic (ring structures) categories. Benzene, a common aromatic hydrocarbon, has a cyclic structure with alternating double bonds, which is important for understanding its chemical properties and reactions in organic chemistry.
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