Problem 62
Choose the larger atom in each pair. a. Sn or Si b. Br or Ga c. Sn or Bi d. Se or Sn
- Arrange these elements in order of increasing atomic radius: F, S, Si, Ge, Ca, Rb.
Problem 63
- Arrange these elements in order of decreasing atomic radius: Cs, Pb, Sb, Se, S.
Problem 64
Problem 65a
Write the electron configuration for each ion. a. O2-
Problem 65b
Write the electron configuration for each ion. b. Br-
Problem 65c,d,e
Write the electron configuration for each ion. c. Sr2+ d. Co3+ e. Cu2+
Problem 66a
Write the electron configuration for each ion. a. Cl-
Problem 66b
Write the electron configuration for each ion. b. P3-
Problem 66c
Write the electron configuration for each ion. c. K+
Problem 66d,e
Write the electron configuration for each ion. d. Mo3+ e. V3+
Problem 67
Write orbital diagrams for each of these ions.Determine if the ion is diamagnetic or paramagnetic. a. V5+ b. Cr3+ c. Ni2+ d. Fe3+
Problem 68
Write orbital diagrams for each ion and determine if the ion is diamagnetic or paramagnetic. a. Cd2+ b. Au+ c. Mo3+ d. Zr2+
Problem 69
Which is the larger species in each pair? a. Li or Li+ b. Cs- or Cs+ c. Cr- or Cr3+ d. O or O2-
Problem 70
Which is the larger species in each pair? a. Sr or Sr2+ b. N or N3- c. Ni or Ni2+ d. S2- or Ca2+
- Arrange this isoelectronic series in order of decreasing radius: O2-, F-, Na+, Mg2+.
Problem 71
Problem 72
Arrange this isoelectronic series in order of increasing atomic radius: Se2- , Sr2+ , Rb+ , Br- .
Problem 73a
Choose the element with the higher first ionization energy from each pair. a. Br or Bi
Problem 73b
Choose the element with the higher first ionization energy from each pair. b. Na or Rb
Problem 73c
Choose the element with the higher first ionization energy from each pair. c. As or At
Problem 73d
Choose the element with the higher first ionization energy from each pair. d. P or Sn
Problem 74
Choose the element with the higher first ionization energy from each pair. a. P or I b. Si or Cl c. P or Sb d. Ga or Ge
Problem 75
Arrange these elements in order of increasing first ionization energy: Si, F, In, N.
- Arrange these elements in order of decreasing first ionization energy: Cl, S, Sn, Pb.
Problem 76
Problem 77
For each element, predict where the 'jump' occurs for successive ionization energies. (For example, does the jump occur between the first and second ionization energies, the second and third, or the third and fourth?) a. Be b. N c. O d. Li
Problem 78
Consider this set of ionization energies. IE1 = 578 kJ/mol IE2 = 1820 kJ/mol IE3 = 2750 kJ/mol IE4 = 11,600 kJ/mol To which third-period element do these ionization values belong?
Problem 79a
Choose the element with the more negative (more exothermic) electron affinity from each pair. a. Na or Rb
Problem 79b
Choose the element with the more negative (more exothermic) electron affinity from each pair. b. B or S
Problem 79c,d
Choose the element with the more negative (more exothermic) electron affinity from each pair. c. C or N d. Li or F
Problem 80
Choose the element with the more negative (more exothermic) electron affinity in each pair. a. Mg or S b. K or Cs c. Si or P d. Ga or Br
Problem 81
Choose the more metallic element from each pair. c. Cl or O
Ch.8 - Periodic Properties of the Elements