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Ch.21 - Organic Chemistry
Chapter 21, Problem 83a

Name each ether. a.

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1
Identify the two alkyl groups attached to the oxygen atom in the ether structure.
Name each alkyl group separately according to the IUPAC nomenclature rules for alkanes, considering any substituents or branches.
Arrange the names of the alkyl groups in alphabetical order, disregarding any prefixes like di, tri, etc., that indicate the number of substituents.
Combine the names of the alkyl groups followed by the word 'ether'. For example, if the alkyl groups are methyl and ethyl, the name of the ether would be 'ethyl methyl ether'.
If the ether is cyclic, it may be named as an oxacycloalkane. Count the total number of carbons in the ring including the oxygen atom, and use the prefix 'oxa' to indicate the presence of oxygen.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Ethers

Ethers are a class of organic compounds characterized by an oxygen atom connected to two alkyl or aryl groups. They have the general formula R-O-R', where R and R' represent hydrocarbon chains. Ethers are known for their relatively low reactivity and are commonly used as solvents in organic chemistry due to their ability to dissolve a wide range of substances.
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Nomenclature of Ethers

The nomenclature of ethers follows specific rules set by the International Union of Pure and Applied Chemistry (IUPAC). Ethers are typically named by identifying the two alkyl or aryl groups attached to the oxygen atom, followed by the word 'ether.' For example, in diethyl ether, the two ethyl groups are named first, indicating their connection through the oxygen atom.
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Common Ethers

Some common examples of ethers include diethyl ether, which is often used as a solvent, and methyl tert-butyl ether (MTBE), used as a fuel additive. Recognizing these common ethers and their applications can help in understanding their significance in both laboratory and industrial settings. Familiarity with these examples aids in the identification and naming of various ethers in chemical contexts.
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