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Ch.21 - Organic Chemistry
Chapter 21, Problem 93b

Determine whether the two structures are isomers or the same molecule drawn in two different ways. b.
Two chemical structures of chlorinated benzene compounds for isomer analysis.

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1
Step 1: Identify the positions of the chlorine atoms on the benzene ring in both structures.
Step 2: For the first structure, note the positions of the chlorine atoms. They are on the 1, 3, and 5 positions of the benzene ring.
Step 3: For the second structure, note the positions of the chlorine atoms. They are on the 1, 2, and 4 positions of the benzene ring.
Step 4: Compare the positions of the chlorine atoms in both structures to determine if they are the same or different.
Step 5: Conclude whether the two structures are isomers (different compounds with the same molecular formula) or the same molecule drawn in different ways based on the positions of the chlorine atoms.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Isomerism

Isomerism refers to the phenomenon where two or more compounds have the same molecular formula but different structural arrangements of atoms. This can lead to variations in physical and chemical properties. Isomers can be classified into structural isomers, which differ in the connectivity of atoms, and stereoisomers, which have the same connectivity but differ in the spatial arrangement of atoms.
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Chlorinated Benzene Compounds

Chlorinated benzene compounds are aromatic hydrocarbons that contain chlorine atoms substituted for hydrogen atoms on a benzene ring. The position of the chlorine substituents can significantly affect the compound's reactivity and properties. Understanding the substitution patterns is crucial for identifying isomers and predicting their behavior in chemical reactions.
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Nomenclature and Structural Representation

Nomenclature in chemistry involves the systematic naming of chemical compounds based on their structure and functional groups. Structural representation, such as Lewis structures, provides a visual depiction of the arrangement of atoms and bonds in a molecule. Familiarity with these conventions is essential for distinguishing between different isomers and understanding their relationships.
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