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Ch.16 - Acids and Bases
Chapter 16, Problem 96a,b,d

Determine whether each anion is basic or neutral. For those anions that are basic, write an equation that shows how the anion acts as a base. a. C7H5O2 b. I d. F

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Identify the conjugate acid of each anion. The conjugate acid of an anion is the species formed when the anion gains a proton (H+).
Determine the strength of the conjugate acid. If the conjugate acid is a weak acid, the anion is likely to be basic. If the conjugate acid is a strong acid, the anion is likely to be neutral.
For C7H5O2, identify the conjugate acid as benzoic acid (C7H6O2), which is a weak acid, indicating that the anion is basic.
For I, identify the conjugate acid as hydroiodic acid (HI), which is a strong acid, indicating that the anion is neutral.
For F, identify the conjugate acid as hydrofluoric acid (HF), which is a weak acid, indicating that the anion is basic. Write the equation for the basic behavior of F: F + H2O ⇌ HF + OH.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Acid-Base Theory

Acid-base theory explains the behavior of substances in terms of proton (H+) transfer. According to the Brønsted-Lowry theory, acids are proton donors, while bases are proton acceptors. Understanding this theory is essential for determining whether an anion can act as a base by accepting protons from acids in solution.
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Basicity of Anions

The basicity of anions refers to their ability to accept protons and form neutral species. Anions derived from weak acids tend to be basic because they can attract protons, while anions from strong acids are typically neutral. Evaluating the strength of the parent acid helps in predicting the basicity of the anion.
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Equilibrium and Reaction Representation

In chemical reactions, equilibrium represents the state where the forward and reverse reactions occur at the same rate. Writing equations that show how anions act as bases involves illustrating the proton transfer process and the resulting equilibrium. This helps in visualizing the anion's role in acid-base reactions.
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