Draw an energy diagram for HCl. Predict the bond order and make a sketch of the lowest energy bonding molecular orbital.
Ch.10 - Chemical Bonding II: Molecular Shapes & Valence Bond Theory
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Tro 4th Edition
Ch.10 - Chemical Bonding II: Molecular Shapes & Valence Bond Theory
Problem 86d



Chapter 10, Problem 86d
The genetic code is based on four different bases with the structures shown here. Assign a geometry and hybridization to each interior atom in these four bases. d. guanine


1
Identify the hybridization of each interior atom by counting the number of sigma bonds and lone pairs around the atom.
For atom 1 (carbonyl carbon), it has 3 sigma bonds and no lone pairs, so it is sp2 hybridized with a trigonal planar geometry.
For atom 2 (nitrogen), it has 2 sigma bonds and 1 lone pair, so it is sp2 hybridized with a bent geometry.
For atom 3 (carbonyl carbon), it has 3 sigma bonds and no lone pairs, so it is sp2 hybridized with a trigonal planar geometry.
For atom 4 (carbon), it has 3 sigma bonds and no lone pairs, so it is sp2 hybridized with a trigonal planar geometry.

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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Hybridization
Hybridization is the concept of mixing atomic orbitals to form new hybrid orbitals that can accommodate the bonding requirements of atoms in a molecule. In guanine, for example, carbon atoms typically exhibit sp2 hybridization, allowing for the formation of planar structures with double bonds, while nitrogen atoms may show sp3 hybridization, accommodating lone pairs and bonding.
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Molecular Geometry
Molecular geometry refers to the three-dimensional arrangement of atoms within a molecule. The geometry is determined by the hybridization of the central atom and the number of bonds and lone pairs surrounding it. For guanine, the arrangement of atoms leads to a specific geometry that influences its interactions and functions in biological systems.
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Resonance Structures
Resonance structures are different ways of drawing a molecule that represent the same arrangement of atoms but differ in the distribution of electrons. In guanine, resonance is important for understanding the delocalization of electrons in the aromatic ring and the stability of the molecule, which is crucial for its role in the genetic code.
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Related Practice
Textbook Question
Textbook Question
The structure of acetylsalicylic acid (aspirin) is shown here. How many π bonds are present in acetylsalicylic acid?
Textbook Question
The structure of acetylsalicylic acid (aspirin) is shown here. How many sigma bonds?
Textbook Question
Most vitamins can be classified as either fat soluble, which results in their tendency to accumulate in the body (so that taking too much can be harmful), or water soluble, which results in their tendency to be quickly eliminated from the body in urine. Examine the structural formulas and space-filling models of these vitamins and determine whether each one is fat soluble (mostly nonpolar) or water soluble (mostly polar). (a) vitamin C