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Ch.22 - The Main Group Elements
Chapter 22, Problem 103

The organ pipes in unheated northern European churches are often observed to be pitted and crumbling to powder in places. Suggest an explanation, given that the pipes are made from tin.

Verified step by step guidance
1
Step 1: Understand the properties of tin. Tin is a metal that can exist in different allotropes, primarily white tin (β-tin) and gray tin (α-tin). White tin is metallic and stable at room temperature, while gray tin is non-metallic and stable at lower temperatures.
Step 2: Consider the environmental conditions. In unheated northern European churches, the temperature can drop significantly, especially during winter months.
Step 3: Explore the concept of 'tin pest.' At low temperatures, white tin can transform into gray tin, a process known as 'tin pest' or 'tin disease.' This transformation causes the metal to become brittle and crumble.
Step 4: Relate the transformation to the observed phenomenon. The pitting and crumbling of the organ pipes can be attributed to the conversion of white tin to gray tin due to the cold temperatures in the unheated churches.
Step 5: Conclude with the impact of temperature on tin. The structural integrity of the organ pipes is compromised as the tin undergoes this phase change, leading to the observed deterioration.

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Corrosion

Corrosion is a chemical process where metals react with environmental factors, leading to deterioration. In the case of tin pipes, exposure to moisture and pollutants can initiate corrosion, resulting in pitting and crumbling. This process is accelerated in environments with high humidity or acidic conditions, which are common in unheated churches.
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Chemical Properties

Tin Oxidation

Tin can oxidize when exposed to air and moisture, forming tin oxide. This oxide layer can protect the underlying metal to some extent, but if the protective layer is compromised, further oxidation can occur, leading to structural weakness. The presence of acidic substances can also enhance this oxidation process, contributing to the degradation of the pipes.
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Oxide Reactions

Environmental Factors

Environmental factors such as temperature, humidity, and the presence of pollutants play a significant role in the corrosion of metals. In northern European churches, the cold and damp conditions can create an ideal environment for corrosion to occur. Additionally, pollutants from the air can react with the metal, exacerbating the deterioration of the tin pipes.
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Conversion Factors