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Ch.22 - Chemistry of the Nonmetals
Chapter 22, Problem 34

Complete the exercises below. Name the following compounds and assign oxidation states to the halogens in them: a. KClO₃, b. Ca(IO₃)₂.

Verified step by step guidance
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Step 1: Identify the compound and its components. For KClO₃, the compound is potassium chlorate, consisting of potassium (K), chlorine (Cl), and oxygen (O). For Ca(IO₃)₂, the compound is calcium iodate, consisting of calcium (Ca), iodine (I), and oxygen (O).
Step 2: Assign known oxidation states. Potassium (K) and calcium (Ca) are alkali and alkaline earth metals, respectively, and typically have oxidation states of +1 and +2. Oxygen (O) usually has an oxidation state of -2.
Step 3: Calculate the oxidation state of the halogen in KClO₃. Let the oxidation state of chlorine (Cl) be x. The sum of oxidation states in a neutral compound is zero. Therefore, for KClO₃: +1 (K) + x (Cl) + 3(-2) (O) = 0.
Step 4: Solve for the oxidation state of chlorine in KClO₃. Rearrange the equation from Step 3 to find x: x = -1 + 6 = +5. Thus, the oxidation state of Cl in KClO₃ is +5.
Step 5: Calculate the oxidation state of iodine in Ca(IO₃)₂. Let the oxidation state of iodine (I) be y. The sum of oxidation states in a neutral compound is zero. Therefore, for Ca(IO₃)₂: +2 (Ca) + 2[y + 3(-2)] (IO₃) = 0. Solve for y to find the oxidation state of iodine.

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Oxidation States

Oxidation states, or oxidation numbers, are a way to keep track of electrons in chemical compounds. They indicate the degree of oxidation of an atom in a substance, helping to determine how electrons are transferred in redox reactions. The oxidation state of an element in a compound can be positive, negative, or zero, depending on its electron gain or loss relative to its elemental form.
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Naming Compounds

Naming compounds involves using systematic rules to assign names based on their chemical composition. For ionic compounds, the cation (positive ion) is named first, followed by the anion (negative ion). In the case of polyatomic ions, such as chlorate in KClO₃, specific naming conventions apply, which are essential for accurately identifying the compound.
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Polyatomic Ions

Polyatomic ions are ions composed of two or more atoms covalently bonded, which carry a net charge. Common examples include sulfate (SO₄²⁻) and nitrate (NO₃⁻). Understanding polyatomic ions is crucial for naming compounds and determining oxidation states, as they often influence the overall charge and structure of the compound.
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