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Ch.8 - Basic Concepts of Chemical Bonding
Chapter 8, Problem 7c

The partial Lewis structure that follows is for a hydrocarbon molecule. In the full Lewis structure, each carbon atom satisfies the octet rule, and there are no unshared electron pairs in the molecule. The carbon—carbon bonds are labeled 1, 2, and 3. (c) Which carbon—carbon bond is the strongest one?

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insert step 1: Understand that the strength of a carbon-carbon bond is related to the type of bond: single, double, or triple.
insert step 2: Recall that a single bond (sigma bond) is weaker than a double bond (one sigma and one pi bond), and a double bond is weaker than a triple bond (one sigma and two pi bonds).
insert step 3: Identify the types of carbon-carbon bonds present in the molecule by analyzing the partial Lewis structure.
insert step 4: Determine which bond is a single, double, or triple bond based on the number of shared electron pairs between the carbon atoms.
insert step 5: Conclude that the strongest carbon-carbon bond is the one with the most shared electron pairs, typically a triple bond.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Octet Rule

The octet rule is a chemical guideline stating that atoms tend to bond in such a way that they each have eight electrons in their valence shell, achieving a stable electron configuration similar to that of noble gases. In hydrocarbons, carbon atoms typically form four bonds to satisfy this rule, influencing the molecule's stability and reactivity.
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Types of Carbon-Carbon Bonds

Carbon atoms can form single, double, or triple bonds with each other, with each type having different strengths and characteristics. Single bonds (sigma bonds) are the weakest, while double bonds (one sigma and one pi bond) are stronger, and triple bonds (one sigma and two pi bonds) are the strongest. The bond strength affects the overall stability of the molecule.
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Bond Strength and Length

Bond strength is inversely related to bond length; shorter bonds are generally stronger due to the increased overlap of atomic orbitals. In hydrocarbons, the presence of multiple bonds (double or triple) results in shorter bond lengths compared to single bonds, making them stronger. Understanding this relationship is crucial for determining which carbon-carbon bond is the strongest.
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