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Ch.6 - Electronic Structure of Atoms
Chapter 6, Problem 105

Microwave ovens use microwave radiation to heat food. The energy of the microwaves is absorbed by water molecules in food and then transferred to other components of the food. (a) Suppose that the microwave radiation has a wavelength of 10 cm. How many photons are required to heat 200 mL of water from 25 to 75 °C?

Verified step by step guidance
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Step 1: Calculate the energy required to heat the water. Use the formula for heat energy: \( q = m \cdot c \cdot \Delta T \), where \( m \) is the mass of the water, \( c \) is the specific heat capacity of water (4.18 J/g°C), and \( \Delta T \) is the change in temperature.
Step 2: Convert the volume of water to mass. Since the density of water is approximately 1 g/mL, 200 mL of water has a mass of 200 g.
Step 3: Calculate the change in temperature \( \Delta T \) as the final temperature minus the initial temperature: \( 75°C - 25°C = 50°C \).
Step 4: Calculate the energy of a single photon using the formula \( E = \frac{hc}{\lambda} \), where \( h \) is Planck's constant (6.626 \times 10^{-34} \text{ J s}), \( c \) is the speed of light (3.00 \times 10^8 \text{ m/s}), and \( \lambda \) is the wavelength of the microwave radiation (10 cm converted to meters).
Step 5: Determine the number of photons required by dividing the total energy calculated in Step 1 by the energy of a single photon calculated in Step 4.

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Photon Energy

The energy of a photon is determined by its wavelength, described by the equation E = hc/λ, where E is energy, h is Planck's constant, c is the speed of light, and λ is the wavelength. For microwaves with a wavelength of 10 cm, this relationship allows us to calculate the energy of each photon, which is essential for determining how many photons are needed to heat the water.
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Specific Heat Capacity

Specific heat capacity is the amount of heat required to raise the temperature of a unit mass of a substance by one degree Celsius. For water, this value is approximately 4.18 J/g°C. Understanding this concept is crucial for calculating the total energy needed to heat 200 mL of water from 25 to 75 °C, as it directly influences the total energy required for the temperature change.
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Energy Transfer in Heating

When microwaves heat food, the energy absorbed by water molecules increases their kinetic energy, leading to a rise in temperature. This energy transfer is key to understanding how the absorbed energy from photons translates into thermal energy, allowing us to calculate the total number of photons needed based on the energy required to achieve the desired temperature increase in the water.
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Related Practice
Textbook Question

Scientists have speculated that element 126 might have a moderate stability, allowing it to be synthesized and characterized. Predict what the condensed electron configuration of this element might be.

Textbook Question

In the experiment shown schematically below, a beam of neutral atoms is passed through a magnetic field. Atoms that have unpaired electrons are deflected in different directions in the magnetic field depending on the value of the electron spin quantum number. In the experiment illustrated, we envision that a beam of hydrogen atoms splits into two beams. (a) What is the significance of the observation that the single beam splits into two beams?

Textbook Question

In the experiment shown schematically below, a beam of neutral atoms is passed through a magnetic field. Atoms that have unpaired electrons are deflected in different directions in the magnetic field depending on the value of the electron spin quantum number. In the experiment illustrated, we envision that a beam of hydrogen atoms splits into two beams. (c) What do you think would happen if the beam of hydrogen atoms were replaced with a beam of helium atoms? Why?

Textbook Question

The discovery of hafnium, element number 72, provided a controversial episode in chemistry. G. Urbain, a French chemist, claimed in 1911 to have isolated an element number 72 from a sample of rare earth (elements 58–71) compounds. However, Niels Bohr believed that hafnium was more likely to be found along with zirconium than with the rare earths. D. Coster and G. von Hevesy, working in Bohr's laboratory in Copenhagen, showed in 1922 that element 72 was present in a sample of Norwegian zircon, an ore of zirconium. (The name hafnium comes from the Latin name for Copenhagen, Hafnia). (a) How would you use electron configuration arguments to justify Bohr's prediction?

Textbook Question

The discovery of hafnium, element number 72, provided a controversial episode in chemistry. G. Urbain, a French chemist, claimed in 1911 to have isolated an element number 72 from a sample of rare earth (elements 58–71) compounds. However, Niels Bohr believed that hafnium was more likely to be found along with zirconium than with the rare earths. D. Coster and G. von Hevesy, working in Bohr's laboratory in Copenhagen, showed in 1922 that element 72 was present in a sample of Norwegian zircon, an ore of zirconium. (The name hafnium comes from the Latin name for Copenhagen, Hafnia). (d) Using their electron configurations, account for the fact that Zr and Hf form chlorides MCl4 and oxides MO2.