Problem 77a
Sodium hydroxide reacts with carbon dioxide as follows: 2 NaOH(s) + CO2(g) → Na2CO3(s) + H2O(l) Which is the limiting reactant when 1.85 mol NaOH and 1.00 mol CO2 are allowed to react?
Problem 77b
Sodium hydroxide reacts with carbon dioxide as follows: 2 NaOH(s) + CO2(g) → Na2CO3(s) + H2O(l) How many moles of Na2CO3 can be produced?
Problem 77c
Sodium hydroxide reacts with carbon dioxide as follows: 2 NaOH1s2 + CO21g2¡Na2CO31s2 + H2O1l2 How many moles of the excess reactant remain after the completion of the reaction?
Problem 78a
Aluminum hydroxide reacts with sulfuric acid as follows: 2 Al1OH231s2 + 3 H2SO41aq2¡Al21SO4231aq2 + 6 H2O1l2 Which is the limiting reactant when 0.500 mol Al1OH23 and 0.500 mol H2SO4 are allowed to react?
Problem 78b
Aluminum hydroxide reacts with sulfuric acid as follows: 2 Al1OH231s2 + 3 H2SO41aq2¡Al21SO4231aq2 + 6 H2O1l2 How many moles of Al21SO423 can form under these conditions?
Problem 78c
Aluminum hydroxide reacts with sulfuric acid as follows: 2 Al1OH231s2 + 3 H2SO41aq2¡Al21SO4231aq2 + 6 H2O1l2 How many moles of the excess reactant remain after the completion of the reaction?
Problem 79
The fizz produced when an Alka-Seltzer tablet is dissolved in water is due to the reaction between sodium bicarbonate 1NaHCO32 and citric acid 1H3C6H5O72: 3 NaHCO31aq2 + H3C6H5O71aq2¡ 3 CO21g2 + 3H2O1l2 + Na3C6H5O71aq2 In a certain experiment 1.00 g of sodium bicarbonate and 1.00 g of citric acid are allowed to react. (a) Which is the limiting reactant? (b) How many grams of carbon dioxide form? (c) How many grams of the excess reactant remain after the limiting reactant is completely consumed?
Problem 80a
One of the steps in the commercial process for converting ammonia to nitric acid is the conversion of NH3 to NO: 4 NH31g2 + 5 O21g2¡4 NO1g2 + 6 H2O1g2 In a certain experiment, 2.00 g of NH3 reacts with 2.50 g of O2. (a) Which is the limiting reactant?
Problem 80c
One of the steps in the commercial process for converting ammonia to nitric acid is the conversion of NH3 to NO: 4 NH31g2 + 5 O21g2¡4 NO1g2 + 6 H2O1g2 In a certain experiment, 2.00 g of NH3 reacts with 2.50 g of O2. (c) How many grams of the excess reactant remain after the limiting reactant is completely consumed?
Problem 80d
One of the steps in the commercial process for converting ammonia to nitric acid is the conversion of NH3 to NO: 4 NH3(g) + 5 O2(g) → 4 NO(g) + 6 H2O(g) In a certain experiment, 2.00 g of NH3 reacts with 2.50 g of O2. (d) Show that your calculations in parts (b) and (c) are consistent with the law of conservation of mass.
Problem 81a
Solutions of sodium carbonate and silver nitrate react to form solid silver carbonate and a solution of sodium nitrate. A solution containing 3.50 g of sodium carbonate is mixed with one containing 5.00 g of silver nitrate. How many grams of sodium carbonate are present after the reaction is complete? How many grams of sodium nitrate are present after the reaction is complete?
Problem 81b
Solutions of sodium carbonate and silver nitrate react to form solid silver carbonate and a solution of sodium nitrate. A solution containing 3.50 g of sodium carbonate is mixed with one containing 5.00 g of silver nitrate. How many grams of silver carbonate are present after the reaction is complete?
Problem 82a
Solutions of sulfuric acid and lead(II) acetate react to form solid lead(II) sulfate and a solution of acetic acid. If 5.00 g of sulfuric acid and 5.00 g of lead(II) acetate are mixed, calculate the number of grams of sulfuric acid and grams of acetic acid present in the mixture after the reaction is complete.
Problem 82b
Solutions of sulfuric acid and lead(II) acetate react to form solid lead(II) sulfate and a solution of acetic acid. If 5.00 g of sulfuric acid and 5.00 g of lead(II) acetate are mixed, calculate the number of grams of lead(II) acetate present in the mixture after the reaction is complete.
Problem 83a
When benzene 1C6H62 reacts with bromine 1Br22, bromobenzene 1C6H5Br2 is obtained: C6H6 + Br2¡C6H5Br + HBr (a) When 30.0 g of benzene reacts with 65.0 g of bromine, what is the theoretical yield of bromobenzene?
Problem 83b
When benzene 1C6H62 reacts with bromine 1Br22, bromobenzene 1C6H5Br2 is obtained: C6H6 + Br2¡C6H5Br + HBr (b) If the actual yield of bromobenzene is 42.3 g, what is the percentage yield?
Problem 84
When ethane 1C2H62 reacts with chlorine 1Cl22, the main product is C2H5Cl, but other products containing Cl, such as C2H4Cl2, are also obtained in small quantities. The formation of these other products reduces the yield of C2H5Cl. (a) Calculate the theoretical yield of C2H5Cl when 125 g of C2H6 reacts with 255 g of Cl2, assuming that C2H6 and Cl2 react only to form C2H2Cl and HCl. (b) Calculate the percent yield of C2H5Cl if the reaction produces 206 g of C2H5Cl.
Problem 85
Hydrogen sulfide is an impurity in natural gas that must be removed. One common removal method is called the Claus process, which relies on the reaction: 8 H2S1g2 + 4 O21g2¡S81l2 + 8 H2O1g2 Under optimal conditions the Claus process gives 98% yield of S8 from H2S. If you started with 30.0 g of H2S and 50.0 g of O2, how many grams of S8 would be produced, assuming 98% yield?
Problem 86
When hydrogen sulfide gas is bubbled into a solution of sodium hydroxide, the reaction forms sodium sulfide and water. How many grams of sodium sulfide are formed if 1.25 g of hydrogen sulfide is bubbled into a solution containing 2.00 g of sodium hydroxide, assuming that the sodium sulfide is made in 92.0% yield?
Problem 87a
Write balanced chemical equations for (a) the complete combustion of acetone (CH3COCH3), a common organic solvent (b) the decomposition of solid mercury (I) carbonate into carbon dioxide gas, mercury, and solid mercury oxide
Problem 87c
Write balanced chemical equations for (c) the combination reaction between nickel metal and chlorine gas.
Problem 88a
If 2.0 mol CH3CH2CH2COOH, 2.0 mol C4H10, and 2.0 mol C6H6 are completely combusted in oxygen, which one produces the largest number of moles of H2O?
Problem 88b
If 2.0 mol CH3CH2CH2COOH, 2.0 mol C4H10, and 2.0 mol C6H6 are completely combusted in oxygen, which one produces the least? Explain.
- Calcium is an essential nutrient in our body. It is important for bone health. Four common calcium-containing supplements are calcium carbonate (CaCO3), calcium citrate (Ca3C12H10O14), calcium gluconate (CaC12H22O14), and calcium lactate (CaC6H10O6). Rank these calcium supplements in terms of the mass percentage of calcium they contain.
Problem 89
Problem 90a
(a) Ibuprofen is a common over-the-counter analgesic with the formula C13H18O2. How many moles of C13H18O2 are in a 500-mg tablet of ibuprofen? Assume the tablet is composed entirely of ibuprofen.
- CdSe quantum dots that are 6.5 nm in diameter emit red light upon stimulation. Assuming that the dot is a perfect sphere, calculate how many Cd atoms are in one quantum dot of this size.
Problem 91
Problem 91a
Very small semiconductor crystals, composed of approximately 1000 to 10,000 atoms, are called quantum dots. Quantum dots made of the semiconductor CdSe are now being used in electronic reader and tablet displays because they emit light efficiently and in multiple colors, depending on dot size. The density of CdSe is 5.82 g/cm3. (a) What is the mass of one 2.5-nm CdSe quantum dot?
Problem 91c
Very small semiconductor crystals, composed of approximately 1000 to 10,000 atoms, are called quantum dots. Quantum dots made of the semiconductor CdSe are now being used in electronic reader and tablet displays because they emit light efficiently and in multiple colors, depending on dot size. The density of CdSe is 5.82 g/cm3. (c) What is the mass of one 6.5-nm CdSe quantum dot?
Problem 91e
Very small semiconductor crystals, composed of approximately 1000 to 10,000 atoms, are called quantum dots. Quantum dots made of the semiconductor CdSe are now being used in electronic reader and tablet displays because they emit light efficiently and in multiple colors, depending on dot size. The density of CdSe is 5.82 g/cm3. (e) If you wanted to make one 6.5-nm dot from multiple 2.5-nm dots, how many 2.5-nm dots would you need, and how many CdSe formula units would be left over, if any?
Problem 92a
(a) One molecule of the antibiotic penicillin G has a mass of 5.342×10-21 g. What is the molar mass of penicillin G?
Ch.3 - Chemical Reactions and Reaction Stoichiometry