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Ch.23 - Transition Metals and Coordination Chemistry
Chapter 23, Problem 13

Complete the exercises below. For each of the following compounds, determine the electron configuration of the transition-metal ion. a. TiO, b. TiO₂, c. NiO, d. ZnO.

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1
Identify the oxidation state of the transition metal in each compound by considering the charges of the other elements. For example, in TiO, oxygen typically has a charge of -2, so titanium must have a charge of +2 to balance the compound.
Determine the electron configuration of the neutral transition metal atom. For example, titanium (Ti) in its neutral state has an electron configuration of [Ar] 3d^2 4s^2.
Remove electrons from the highest energy level orbitals to account for the oxidation state. For transition metals, electrons are typically removed from the s orbital before the d orbital. For Ti^2+, remove two electrons from the 4s orbital, resulting in [Ar] 3d^2.
Repeat the process for each compound, considering the oxidation state of the transition metal in each case. For example, in TiO₂, titanium is in the +4 oxidation state, so remove four electrons from the 4s and 3d orbitals.
For NiO, nickel is in the +2 oxidation state, so remove two electrons from the 4s orbital of the neutral nickel atom, which has an electron configuration of [Ar] 3d^8 4s^2, resulting in [Ar] 3d^8. For ZnO, zinc is in the +2 oxidation state, so remove two electrons from the 4s orbital of the neutral zinc atom, which has an electron configuration of [Ar] 3d^10 4s^2, resulting in [Ar] 3d^10.

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Electron Configuration

Electron configuration describes the distribution of electrons in an atom's orbitals. It follows the Aufbau principle, which states that electrons fill lower-energy orbitals first, and is represented using a notation that indicates the energy levels and sublevels occupied by electrons. Understanding electron configuration is crucial for predicting the chemical behavior and properties of elements, especially transition metals.
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Transition Metals

Transition metals are elements found in the d-block of the periodic table, characterized by their ability to form variable oxidation states and complex ions. They typically have partially filled d orbitals, which play a significant role in their chemical reactivity and bonding. Transition metals often exhibit unique properties such as colored compounds and catalytic activity, making their electron configurations particularly important in understanding their behavior in compounds.
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Ionic Compounds and Oxidation States

Ionic compounds are formed when metals transfer electrons to nonmetals, resulting in the formation of cations and anions. The oxidation state of an element in a compound indicates the charge it would have if the compound were composed of ions. For transition metals, determining the oxidation state is essential for correctly writing the electron configuration of their ions, as it affects the number of electrons removed from the neutral atom.
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