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Ch.21 - Nuclear Chemistry
Chapter 21, Problem 88

Calculate the mass of octane, C8H18, that must be burned in air to evolve the same quantity of energy as produced by the fusion of 1.0 g of hydrogen in the following fusion reaction: 4 1^1H → 4 2He + 2 0^1e. Assume that all the products of the combustion of octane are in their gas phases. Use data from Exercise 21.50, Appendix C, and the inside covers of the text. The standard enthalpy of formation of octane is -250.1 kJ/mol.

Verified step by step guidance
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Step 1: Calculate the energy released by the fusion of 1.0 g of hydrogen. Use the given fusion reaction: 4 1^1H → 4 2He + 2 0^1e. Determine the energy released per mole of hydrogen atoms and then convert this to the energy released per gram of hydrogen.
Step 2: Determine the energy released per mole of octane (C8H18) during combustion. Use the standard enthalpy of formation of octane (-250.1 kJ/mol) and the balanced chemical equation for the combustion of octane: 2 C8H18 + 25 O2 → 16 CO2 + 18 H2O.
Step 3: Calculate the total energy released by burning one mole of octane. This involves using the enthalpy change of the combustion reaction, which can be found by using the standard enthalpies of formation for CO2 and H2O from Appendix C.
Step 4: Compare the energy released by the fusion of hydrogen to the energy released by the combustion of octane. Set up a proportion to find the mass of octane needed to release the same amount of energy as the fusion of 1.0 g of hydrogen.
Step 5: Solve the proportion to find the mass of octane required. Use the molar mass of octane (C8H18) to convert from moles to grams, ensuring that the energy released by the combustion of this mass of octane matches the energy released by the fusion of hydrogen.

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Combustion Reaction

A combustion reaction is a chemical process in which a substance (typically a hydrocarbon) reacts with oxygen to produce carbon dioxide, water, and energy. In this case, octane (C8H18) combusts in air, releasing energy that can be quantified using its standard enthalpy of formation. Understanding the stoichiometry of the combustion reaction is essential for calculating the mass of octane needed to match the energy produced by another reaction.
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Enthalpy of Formation

The enthalpy of formation is the change in enthalpy when one mole of a compound is formed from its elements in their standard states. For octane, the standard enthalpy of formation is given as -250.1 kJ/mol, indicating that energy is released when octane is formed. This value is crucial for calculating the energy released during combustion, which is necessary to determine how much octane must be burned to match the energy from the fusion of hydrogen.
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Energy from Fusion

The energy released during nuclear fusion, such as the fusion of hydrogen into helium, is significantly greater than that from chemical reactions. In the given fusion reaction, 4 hydrogen nuclei combine to form helium, releasing a substantial amount of energy. To solve the problem, one must first calculate the energy produced from the fusion of 1.0 g of hydrogen and then relate this to the energy released from the combustion of octane to find the required mass.
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