You make a solution of a nonvolatile solute with a liquid solvent. Indicate if each of the following statements is true or false. (d) The boiling point of the solution increases in proportion to the concentration of the solute. (e) At any temperature, the vapor pressure of the solvent over the solution is lower than what it would be for the pure solvent.
Verified step by step guidance
1
Understand the concept of boiling point elevation: When a nonvolatile solute is added to a solvent, the boiling point of the solution increases. This is known as boiling point elevation.
Recall the formula for boiling point elevation: \( \Delta T_b = i \cdot K_b \cdot m \), where \( \Delta T_b \) is the boiling point elevation, \( i \) is the van't Hoff factor, \( K_b \) is the ebullioscopic constant of the solvent, and \( m \) is the molality of the solution.
Note that the boiling point elevation is directly proportional to the molality of the solution, which is a measure of the concentration of the solute.
Consider that the statement 'The boiling point of the solution increases in proportion to the concentration of the solute' aligns with the concept of boiling point elevation being proportional to solute concentration.
Conclude that the statement is true based on the relationship between solute concentration and boiling point elevation.
Verified video answer for a similar problem:
This video solution was recommended by our tutors as helpful for the problem above.
Video duration:
1m
Play a video:
Was this helpful?
Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Colligative Properties
Colligative properties are properties of solutions that depend on the number of solute particles in a given amount of solvent, rather than the identity of the solute. These properties include boiling point elevation, freezing point depression, vapor pressure lowering, and osmotic pressure. Understanding colligative properties is essential for predicting how the addition of a solute affects the physical properties of a solvent.
Boiling point elevation is a specific colligative property that describes how the boiling point of a solvent increases when a nonvolatile solute is added. The increase in boiling point is directly proportional to the molal concentration of the solute, as described by the formula ΔT_b = i * K_b * m, where ΔT_b is the boiling point elevation, K_b is the ebullioscopic constant, and m is the molality of the solution.
A nonvolatile solute is a substance that does not readily evaporate and has a negligible vapor pressure compared to that of the solvent. When a nonvolatile solute is dissolved in a solvent, it disrupts the solvent's ability to vaporize, leading to changes in the solution's boiling point and other colligative properties. This characteristic is crucial for understanding how solutes affect solvent behavior in solutions.