(a) After the label fell off a bottle containing a clear liquid believed to be benzene, a chemist measured the density of the liquid to verify its identity. A 25.0-mL portion of the liquid had a mass of 21.95 g. A chemistry handbook lists the density of benzene at 15 °C as 0.8787 g/mL. Is the calculated density in agreement with the tabulated value?
If on a certain year, an estimated amount of 4 million metrictons (1 metric ton = 1000 kg) of nitrous oxide 1N2O2 wasemitted worldwide due to agricultural activities, express thismass of N2O in grams without exponential notation, usingan appropriate metric prefix.


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Key Concepts
Unit Conversion
Metric Prefixes
Mass of Nitrous Oxide (N2O)
(b) An experiment requires 15.0 g of cyclohexane, whose density at 25 C is 0.7781 g>mL. What volume of cyclohexane should be used?
(c) A spherical ball of lead has a diameter of 5.0 cm. What is the mass of the sphere if lead has a density of 11.34 g>cm3? (The volume of a sphere is 14>32pr3, where r is the radius.)
Use of the British thermal unit (Btu) is common in some types of engineering work. A Btu is the amount of heat required to raise the temperature of 1 lb of water by 1°F. Calculate the number of joules in a Btu.
A watt is a measure of power (the rate of energy change) equal to 1 J/s. (a) Calculate the number of joules in a kilowatt-hour.
A watt is a measure of power (the rate of energy change) equal to 1 J/s. (b) An adult person radiates heat to the surroundings at about the same rate as a 100-watt electric incandescent light bulb. What is the total amount of energy in kcal radiated to the surroundings by an adult over a 24 h period?