Entropy Calculations definitions Flashcards
Entropy Calculations definitions
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Entropy
A measure of disorder or randomness, typically in units of joules per Kelvin.Second Law of Thermodynamics
States that the entropy of the universe tends to increase, indicating spontaneous processes.Spontaneous Process
A process with a positive total entropy change in the universe, aligning with natural tendencies.Non-Spontaneous Process
A process with a negative total entropy change in the universe, opposing natural tendencies.Equilibrium
A state where the total entropy change in the universe is zero, indicating no net change.Standard Molar Entropy
The entropy of a substance in its standard state, always greater than zero.ΔSuniverse
The sum of the entropy change of the system and surroundings, indicating spontaneity.ΔSsystem
The entropy change of the system, often calculated using standard molar entropies.ΔSsurroundings
Calculated as the negative change in enthalpy of the reaction divided by temperature.ΔHreaction
The change in enthalpy of a reaction, typically in kilojoules, used in entropy calculations.Standard Conditions
Conditions of 25 degrees Celsius and 1 atmosphere pressure for measuring standard entropies.Joules per Kelvin
The unit of measurement for entropy, indicating energy per temperature increment.Sigma
Represents the summation of terms, used in calculating standard entropy changes.Moles
A unit representing the amount of substance, used in calculating entropy changes.Products minus Reactants
The method for calculating the standard entropy change of a reaction.