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Multiple Choice
Which of the following statements is/are true? I. The hydrocarbon methane (CH4) will dissolve completely in acetone (CH3COCH3). II. Ammonia (NH3) will form a heterogeneous mixture with carbon tetrachloride (CCl4). III. Pentane (C5H12) will form a homogeneous mixture with carbon tetrabromide (CBr4). IV. Methanethiol (CH3SH) is miscible in fluoromethane (CH3F).
A
I only
B
II and III
C
II, III, IV
D
III and IV
E
None of the above
Verified step by step guidance
1
Step 1: Understand the concept of solubility and miscibility. Solubility refers to the ability of a substance to dissolve in a solvent, forming a homogeneous solution. Miscibility is a specific type of solubility where two liquids can mix in any proportion without separating.
Step 2: Analyze statement I. Methane (CH4) is a nonpolar molecule, while acetone (CH3COCH3) is a polar solvent. Generally, nonpolar substances do not dissolve well in polar solvents due to the 'like dissolves like' principle.
Step 3: Analyze statement II. Ammonia (NH3) is a polar molecule, and carbon tetrachloride (CCl4) is nonpolar. Polar and nonpolar substances typically do not mix well, leading to a heterogeneous mixture.
Step 4: Analyze statement III. Pentane (C5H12) and carbon tetrabromide (CBr4) are both nonpolar molecules. Nonpolar substances tend to mix well with each other, forming a homogeneous mixture.
Step 5: Analyze statement IV. Methanethiol (CH3SH) and fluoromethane (CH3F) are both polar molecules. Polar substances are generally miscible with each other, meaning they can mix in all proportions.