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Ch.4 - Reactions in Aqueous Solution
Chapter 4, Problem 88c

A solution is made by mixing 1.5 g of Sr(OH)2 and 23.5 mL of 1.000 M HNO3. (c) Is the resulting solution acidic or basic?

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Calculate the number of moles of Sr(OH)2 by using its molar mass. The molar mass of Sr(OH)2 is calculated as follows: Sr = 87.62 g/mol, O = 16.00 g/mol, H = 1.01 g/mol. Thus, the molar mass of Sr(OH)2 = 87.62 + (16.00*2) + (1.01*2) = 121.64 g/mol. Use the formula: moles = mass / molar mass.
Calculate the number of moles of HNO3 using the concentration and volume. Convert the volume from mL to L by dividing by 1000. Then use the formula: moles = concentration (M) * volume (L).
Compare the moles of Sr(OH)2 and HNO3 to determine the limiting reactant. The reaction between Sr(OH)2 and HNO3 is a neutralization reaction, where Sr(OH)2 reacts with 2 moles of HNO3 for every mole of Sr(OH)2.
Determine if there is any excess reactant. If there are more moles of Sr(OH)2 than required to completely react with the available moles of HNO3, Sr(OH)2 is in excess and the solution will be basic. Conversely, if there are more moles of HNO3 than required to react with Sr(OH)2, HNO3 is in excess and the solution will be acidic.
Conclude whether the solution is acidic or basic based on which reactant is in excess.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Acid-Base Reactions

Acid-base reactions involve the transfer of protons (H+) between reactants. In this case, Sr(OH)2 is a strong base that dissociates in solution to produce hydroxide ions (OH-), while HNO3 is a strong acid that dissociates to produce hydrogen ions (H+). The resulting pH of the solution will depend on the relative amounts of acid and base present.
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Stoichiometry

Stoichiometry is the calculation of reactants and products in chemical reactions. To determine whether the solution is acidic or basic, one must calculate the moles of Sr(OH)2 and HNO3. This involves converting grams of Sr(OH)2 to moles and using the molarity of HNO3 to find its moles, allowing for a comparison of the acid and base present in the solution.
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pH Scale

The pH scale measures the acidity or basicity of a solution, ranging from 0 (very acidic) to 14 (very basic), with 7 being neutral. A solution is considered acidic if its pH is less than 7 and basic if its pH is greater than 7. After determining the moles of acid and base, the resulting pH can be calculated to classify the solution accordingly.
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Related Practice
Textbook Question

A solution of 100.0 mL of 0.200 M KOH is mixed with a solution of 200.0 mL of 0.150 M NiSO4. (b) What precipitate forms?

Textbook Question

A solution of 100.0 mL of 0.200 M KOH is mixed with a solution of 200.0 mL of 0.150 M NiSO4. (e) What is the concentration of each ion that remains in solution?

Textbook Question

A solution is made by mixing 1.5 g of LiOH and 23.5 mL of 1.000 M HNO3. (b) Calculate the concentration of each ion remaining in solution.

Textbook Question

A 0.5895-g sample of impure magnesium hydroxide is dissolved in 100.0 mL of 0.2050 M HCl solution. The excess acid then needs 19.85 mL of 0.1020 M NaOH for neutralization. Calculate the percentage by mass of magnesium hydroxide in the sample, assuming that it is the only substance reacting with the HCl solution.

Textbook Question

A 1.248-g sample of limestone rock is pulverized and then treated with 30.00 mL of 1.035 M HCl solution. The excess acid then requires 11.56 mL of 1.010 M NaOH for neutralization. Calculate the percentage by mass of calcium carbonate in the rock, assuming that it is the only substance reacting with the HCl solution.

Textbook Question

Uranium hexafluoride, UF6, is processed to produce fuel for nuclear reactors and nuclear weapons. UF6 can be produced in a two-step reaction. Solid uranium (IV) oxide, UO2, is first made to react with hydrofluoric acid (HF) solution to form solid UF4 with water as a by-product. UF4 further reacts with fluorine gas to form UF6. (a) Write the balanced molecular equations for the conversion of UO2 into UF4 and the conversion of UF4 to UF6. (b) Which step is an acid-base reaction?