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Multiple Choice
Which of the following methods can be used to estimate the pH of a weak base solution if the pKa values are not provided?
A
Use the Henderson-Hasselbalch equation
B
Use the Kb value and the initial concentration to calculate pH
C
Estimate pH using the average of pKa values
D
Assume complete dissociation and use the pH = 7
Verified step by step guidance
1
Identify that the problem involves estimating the pH of a weak base solution without pKa values.
Recognize that the Henderson-Hasselbalch equation requires pKa values, which are not provided, so this method is not applicable.
Understand that assuming complete dissociation and using pH = 7 is incorrect for weak bases, as they do not fully dissociate and typically have a pH greater than 7.
Realize that estimating pH using the average of pKa values is not possible without the pKa values themselves.
Conclude that the correct method is to use the Kb value and the initial concentration of the weak base to calculate the pH. This involves setting up an equilibrium expression using the Kb value and solving for the concentration of OH⁻ ions, then converting this to pH.