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Multiple Choice
What is the empirical formula for a compound containing 34.4% ethylenediamine, 2.101% Ni, 3.44% sulfate, and 60.06% water by mass?
A
C2H8N2Ni(SO4)2·6H2O
B
C2H8N2NiSO4·6H2O
C
C2H8N2NiSO4·4H2O
D
C2H4N2NiSO4·6H2O
Verified step by step guidance
1
Step 1: Convert the percentage composition of each component to grams, assuming you have 100 grams of the compound. This means you have 34.4 grams of ethylenediamine, 2.101 grams of Ni, 3.44 grams of sulfate, and 60.06 grams of water.
Step 2: Calculate the moles of each component. Use the molar mass of each component: ethylenediamine (C2H8N2), Ni, sulfate (SO4), and water (H2O). For example, moles of ethylenediamine = 34.4 g / molar mass of C2H8N2.
Step 3: Determine the simplest whole number ratio of moles of each component. Divide the moles of each component by the smallest number of moles calculated in the previous step.
Step 4: Use the whole number ratios to write the empirical formula. The empirical formula is the simplest ratio of the elements in the compound.
Step 5: Verify the empirical formula by checking if the calculated formula matches one of the given options. Consider the hydration number (number of water molecules) in the formula as well.