Calculate the volume (mL) of acetone, C₃ H₆ O, (density = 0.786 g/mL) that can be vaporized at its normal boiling point with 345 kJ of heat. ΔH_vap for acetone is 29.1 kJ/mol.

Draw a heating curve (such as the one in Figure 11.36) for 1 mole of methanol beginning at 170 K and ending at 350 K. Assume that the values given here are constant over the relevant temperature ranges. Melting point: 176 K, Boiling point: 338 K, ΔH_fus: 2.2 kJ/mol, ΔH_vap: 35.2 kJ/mol, C_s,solid: 105 J/mol·K, C_s,liquid: 81.3 J/mol·K, C_s,gas: 48 J/mol·K.

Draw a heating curve (such as the one in Figure 11.36) for 1 mol of benzene beginning at 0 °C and ending at 100 °C. Assume that the values given here are constant over the relevant temperature ranges: Melting point 5.4 °C, Boiling point 80.1 °C, ΔHfus 9.9 kJ/mol, ΔHvap 30.7 kJ/mol, Cs,solid 118 J/mol⋅K, Cs,liquid 135 J/mol⋅K, Cs,gas 104 J/mol⋅K.

Determine the vapor pressure (atm) of rubbing alcohol (isopropanol) at 20.0℃. The normal boiling point of isopropanol is 82.3℃ and the heat of vaporization (ΔH_vap) is 39.9 kJ/mol.

If 42.0 kJ of heat is added to a 32.0-g sample of liquid meth-ane under 1 atm of pressure at a temperature of -170°C, what are the final state and temperature of the methane once the system equilibrates? Assume no heat is lost to the surroundings. The normal boiling point of methane is -161.5 °C. The specific heats of liquid and gaseous methane are 3.48 and 2.22 J/g-K, respectively. [Section 11.3]

Consider a compound that has a melting point at 65 °C and a boiling point at 175 °C. Which of the following images represents a heating curve for the compound from 40 °C to 200 °C? (LO 11.5)

Why is the heat of sublimation, ΔHsubl, equal to the sum of ΔHvap and ΔHfusion at the same temperature?