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Ch.4 - Reactions in Aqueous Solution
Chapter 4, Problem 100c

If 23.9 mL of the strontium hydroxide solution was needed to neutralize a 37.5 mL aliquot of the nitric acid solution, what is the concentration (molarity) of the acid?

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1
Identify the balanced chemical equation for the reaction: \( \text{Sr(OH)}_2 + 2\text{HNO}_3 \rightarrow \text{Sr(NO}_3)_2 + 2\text{H}_2\text{O} \).
Determine the moles of \( \text{Sr(OH)}_2 \) used: Use the volume (23.9 mL) and molarity of the \( \text{Sr(OH)}_2 \) solution (if given) to calculate moles using \( \text{moles} = \text{molarity} \times \text{volume in liters} \).
Use the stoichiometry from the balanced equation to find the moles of \( \text{HNO}_3 \): Since 1 mole of \( \text{Sr(OH)}_2 \) reacts with 2 moles of \( \text{HNO}_3 \), multiply the moles of \( \text{Sr(OH)}_2 \) by 2.
Calculate the molarity of the \( \text{HNO}_3 \) solution: Use the moles of \( \text{HNO}_3 \) and the volume of the \( \text{HNO}_3 \) solution (37.5 mL converted to liters) to find molarity using \( \text{molarity} = \frac{\text{moles}}{\text{volume in liters}} \).
Review the calculations to ensure all units are consistent and the stoichiometry is correctly applied.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Neutralization Reaction

A neutralization reaction occurs when an acid reacts with a base to produce water and a salt. In this case, strontium hydroxide (a base) neutralizes nitric acid (an acid). The reaction can be represented as: Sr(OH)2 + 2HNO3 → Sr(NO3)2 + 2H2O, illustrating the stoichiometric relationship between the reactants.
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Molarity

Molarity (M) is a measure of concentration defined as the number of moles of solute per liter of solution. It is crucial for calculating the concentration of the nitric acid in this problem. The formula for molarity is M = moles of solute / volume of solution in liters, which allows for the determination of the acid's concentration after the neutralization reaction.
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Stoichiometry

Stoichiometry involves the calculation of reactants and products in chemical reactions based on balanced equations. In this scenario, the stoichiometric coefficients from the balanced neutralization reaction are used to relate the volumes and concentrations of the acid and base, enabling the calculation of the molarity of the nitric acid solution.
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Related Practice
Textbook Question

Hard water contains Ca2+, Mg2+, and Fe2+, which interfere with the action of soap and leave an insoluble coating on the insides of containers and pipes when heated. Water softeners replace these ions with Na+. Keep in mind that charge balance must be maintained. (b) If the sodium is added to the water softener in the form of NaCl, how many grams of sodium chloride are needed?

Textbook Question

Tartaric acid, H2C4H4O6, has two acidic hydrogens. The acid is often present in wines, and a salt derived from the acid precipitates from solution as the wine ages. A solution containing an unknown concentration of the acid is titrated with NaOH. It requires 24.65 mL of 0.2500 M NaOH solution to titrate both acidic protons in 50.00 mL of the tartaric acid solution. Write a balanced net ionic equation for the neutralization reaction

Textbook Question

Tartaric acid, H2C4H4O6, has two acidic hydrogens. The acid is often present in wines, and a salt derived from the acid precipitates from solution as the wine ages. A solution containing an unknown concentration of the acid is titrated with NaOH. It requires 24.65 mL of 0.2500 M NaOH solution to titrate both acidic protons in 50.00 mL of the tartaric acid solution. Calculate the molarity of the tartaric acid solution.

Textbook Question

A solid sample of Zn(OH)2 is added to 0.350 L of 0.500 M aqueous HBr. The solution that remains is still acidic. It is then titrated with 0.500 M NaOH solution, and it takes 88.5 mL of the NaOH solution to reach the equivalence point. What mass of Zn(OH)2 was added to the HBr solution?

Textbook Question

Suppose you have 5.00 g of powdered magnesium metal, 1.00 L of 2.00 M potassium nitrate solution, and 1.00 L of 2.00 M silver nitrate solution. d. What is the molarity of the Mg2+ ions in the resulting solution?

Textbook Question

(a) By titration, 15.0 mL of 0.1008 M sodium hydroxide is needed to neutralize a 0.2053-g sample of a weak acid. What is the molar mass of the acid if it is monoprotic?