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Multiple Choice
Which gas will have a faster rate of effusion according to Graham's law?
A
Helium (He)
B
Nitrogen (N2)
C
Carbon dioxide (CO2)
D
Oxygen (O2)
Verified step by step guidance
1
Understand Graham's Law of Effusion, which states that the rate of effusion of a gas is inversely proportional to the square root of its molar mass. Mathematically, this can be expressed as: , where r and r' are the rates of effusion of two gases, and M and M' are their molar masses.
Identify the molar masses of the gases in question: Helium (He) has a molar mass of approximately 4 g/mol, Nitrogen (N2) has a molar mass of approximately 28 g/mol, Carbon dioxide (CO2) has a molar mass of approximately 44 g/mol, and Oxygen (O2) has a molar mass of approximately 32 g/mol.
Apply Graham's Law to compare the rate of effusion of Helium with each of the other gases. Since the rate of effusion is inversely proportional to the square root of the molar mass, the gas with the smallest molar mass will effuse the fastest.
Calculate the square root of the molar masses for each gas to determine their relative rates of effusion. For example, for Helium, calculate , and compare it with for Nitrogen, for Carbon dioxide, and for Oxygen.
Conclude that the gas with the smallest square root of its molar mass will have the fastest rate of effusion. In this case, Helium, with the smallest molar mass, will effuse faster than Nitrogen, Carbon dioxide, and Oxygen.