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Ch.4 - Reactions in Aqueous Solution
Chapter 4, Problem 105b

Suppose you have 3.00 g of powdered zinc metal, 3.00g of powdered silver metal and 500.0 mL of a 0.2 M copper(II) nitrate solution. (b) What is the net ionic equation that describes this reaction?

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Identify the possible reactions: Zinc and silver metals can react with copper(II) nitrate solution. However, silver is less reactive than copper, so it will not displace copper from its compound. Zinc, being more reactive, can displace copper from copper(II) nitrate.
Write the balanced chemical equation for the reaction between zinc and copper(II) nitrate: \( \text{Zn(s)} + \text{Cu(NO}_3\text{)}_2\text{(aq)} \rightarrow \text{Cu(s)} + \text{Zn(NO}_3\text{)}_2\text{(aq)} \).
Identify the ions present in the solution: Copper(II) nitrate dissociates into \( \text{Cu}^{2+} \) and \( \text{NO}_3^- \) ions in solution.
Determine the net ionic equation: The net ionic equation includes only the species that undergo a change. Zinc metal reacts with copper ions, so the net ionic equation is \( \text{Zn(s)} + \text{Cu}^{2+}\text{(aq)} \rightarrow \text{Cu(s)} + \text{Zn}^{2+}\text{(aq)} \).
Verify the charge and mass balance: Ensure that the number of atoms and the total charge are balanced on both sides of the net ionic equation.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Net Ionic Equations

A net ionic equation represents the actual chemical species that participate in a reaction, omitting spectator ions that do not change during the reaction. It focuses on the ions and molecules that undergo a chemical change, providing a clearer picture of the reaction's essence. This is particularly useful in reactions involving soluble ionic compounds in aqueous solutions.
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Oxidation-Reduction Reactions

Oxidation-reduction (redox) reactions involve the transfer of electrons between species, leading to changes in oxidation states. In this context, zinc is oxidized (loses electrons) while copper ions are reduced (gain electrons). Understanding the roles of oxidizing and reducing agents is crucial for writing the correct net ionic equation for the reaction.
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Solubility Rules

Solubility rules help predict whether a compound will dissolve in water, which is essential for determining the reactants and products in aqueous reactions. For instance, copper(II) nitrate is soluble, while silver may form an insoluble compound with certain anions. Knowing these rules aids in identifying which ions remain in solution and which precipitate out during the reaction.
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