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Ch.6 - Ionic Compounds: Periodic Trends and Bonding Theory
McMurry - Chemistry 8th Edition
McMurry8th EditionChemistryISBN: 9781292336145Not the one you use?Change textbook
All textbooksMcMurry 8th EditionCh.6 - Ionic Compounds: Periodic Trends and Bonding TheoryProblem 100
Chapter 6, Problem 100

Many early chemists noted a diagonal relationship among ele-ments in the periodic table, whereby a given element is some-times more similar to the element below and to the right than it is to the element directly below. Lithium is more similar to magnesium than to sodium, for example, and boron is more similar to silicon than to aluminum. Use your knowledge about the periodic trends of such properties as atomic radii and Zeff to explain the existence of diagonal relationships.

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Understand the concept of diagonal relationships: In the periodic table, elements in the same group (vertical column) typically have similar properties. However, some elements show similarities with elements in the next period and group, forming a diagonal relationship.
Consider atomic radii: As you move across a period from left to right, atomic radii decrease due to increased effective nuclear charge (Z_eff), which pulls electrons closer to the nucleus. As you move down a group, atomic radii increase due to the addition of electron shells.
Examine effective nuclear charge (Z_eff): Z_eff is the net positive charge experienced by valence electrons. It increases across a period as protons are added to the nucleus, but remains relatively constant down a group because the increase in nuclear charge is offset by increased electron shielding.
Relate these trends to diagonal relationships: Elements diagonally related (e.g., lithium and magnesium) have similar Z_eff and atomic radii because the increase in Z_eff across a period is balanced by the increase in atomic size down a group, leading to similar chemical properties.
Apply this understanding to specific examples: For lithium and magnesium, both have similar Z_eff and atomic radii, making their chemical properties more alike than lithium and sodium, which are in the same group but have different Z_eff and atomic radii.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Periodic Trends

Periodic trends refer to the predictable patterns observed in the properties of elements as you move across or down the periodic table. Key trends include atomic radius, ionization energy, and electronegativity. Understanding these trends helps explain why certain elements exhibit similar properties, even if they are not in the same group.
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Atomic Radius

Atomic radius is the distance from the nucleus of an atom to the outermost electron shell. As you move down a group in the periodic table, the atomic radius increases due to the addition of electron shells. Conversely, moving across a period from left to right generally decreases the atomic radius due to increased nuclear charge, which pulls electrons closer to the nucleus.
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Effective Nuclear Charge (Zeff)

Effective nuclear charge (Zeff) is the net positive charge experienced by an electron in a multi-electron atom. It accounts for the shielding effect of inner-shell electrons. As Zeff increases across a period, it leads to stronger attraction between the nucleus and valence electrons, influencing properties like atomic size and ionization energy, which are crucial for understanding diagonal relationships.
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Related Practice
Textbook Question
Consider the electronic structure of the element bismuth.(d) Would you expect element 115 to have an ionization ene-rgy greater than, equal to, or less than that of bismuth? Explain.
Textbook Question
Cesium has the smallest ionization energy of all elements (376 kJ/mol), and chlorine has the most negative electron affinity 1-349 kJ/mol2. Will a cesium atom transfer an electron to a chlorine atom to form isolated Cs+1g2 and Cl-1g2 ions? Explain.
Textbook Question
How does electron shielding in multielectron atoms give rise to energy differences among 3s, 3p, and 3d orbitals?
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Textbook Question
Order the electrons in the following orbitals according to their shielding ability: 4s, 4d, 4f.
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Textbook Question
Heating elemental cesium and platinum together for two days at 973 K gives a dark red ionic compound that is 57.67% Cs and 42.33% Pt. (c) What are the charge and electron configuration of the platinum ion?
Textbook Question

Consider the electronic structure of the element bismuth. (a) The first ionization energy of bismuth is Ei1 = +703 kJ/ mol. What is the longest possible wavelength of light that could ionize an atom of bismuth?

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