Table of contents
- 1. Chemical Measurements1h 50m
- 2. Tools of the Trade1h 17m
- 3. Experimental Error1h 52m
- 4 & 5. Statistics, Quality Assurance and Calibration Methods1h 57m
- 6. Chemical Equilibrium3h 41m
- 7. Activity and the Systematic Treatment of Equilibrium1h 0m
- 8. Monoprotic Acid-Base Equilibria1h 53m
- 9. Polyprotic Acid-Base Equilibria2h 17m
- 10. Acid-Base Titrations2h 37m
- 11. EDTA Titrations1h 34m
- 12. Advanced Topics in Equilibrium1h 16m
- 13. Fundamentals of Electrochemistry2h 19m
- 14. Electrodes and Potentiometry41m
- 15. Redox Titrations1h 14m
- 16. Electroanalytical Techniques57m
- 17. Fundamentals of Spectrophotometry50m
6. Chemical Equilibrium
Le Chatelier's Principle
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Join thousands of students who trust us to help them ace their exams!Watch the first videoMultiple Choice
The reaction 2 NaHCO3 (s) ⇌ Na2CO3 (s) + H2O (g) + CO2 (g) is endothermic. What would you do in order to maximize the yield of Na2CO3 (s)?
A
Lower the temperature and increase the volume of the container.
B
Raise the temperature and add CO2(g) and H2O(g).
C
Lower the temperature and decrease the volume of the container.
D
Add CO2(g) and H2O(g) and increase the volume of the container.
E
Increase the volume of the container and raise the temperature.

1
Identify the nature of the reaction: The given reaction is endothermic, meaning it absorbs heat. According to Le Chatelier's principle, increasing the temperature will favor the formation of products in an endothermic reaction.
Analyze the reaction equation: 2 NaHCO3 (s) ⇌ Na2CO3 (s) + H2O (g) + CO2 (g). Notice that the reaction produces gases (H2O and CO2) on the product side.
Consider the effect of volume change: Increasing the volume of the container will decrease the pressure. According to Le Chatelier's principle, the system will shift towards the side with more moles of gas to counteract this change, which is the product side in this case.
Combine the effects of temperature and volume: Raising the temperature and increasing the volume both shift the equilibrium towards the products, maximizing the yield of Na2CO3 (s).
Conclude the strategy: To maximize the yield of Na2CO3 (s), increase the volume of the container and raise the temperature, as both actions favor the formation of products in this endothermic reaction.
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